上学期物理有机下学期the theory of pericyclic reaction-lecture1 to students.pptx

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黄 正

上海有机化学研究所

金属有机国家重点实验室

地址:君谋楼1103

电话Email:huangzh@sioc.ac.cn

;Pericyclic Reaction;R B. Woodward

BS and PhD at MIT, Postdoc at UIUC

1965 Nobel prize for Total Synthesis (奎宁、胆固醇、可的松…)

Established Orbital Correlation Diagrams with Hoffmann. Woodward Hoffmann rule (Crorotation, disrotation)

Deduce the structure of ferrocene based on its reactivity with G. Wilkinson.

Structure, mechanism, synthesis

Students or postdocs: Kishi, Foote, Houk, Breslow, Schreiber, Roush…;物理有机化学家;Saul Winstein: 1912-1969. Proposed a three-center two-electron bond structure of 2-nobonyl cation. Argued by H. C. Brown who supported a classis resonance structure. Investigated by Low T NMR, Raman …Changed the view of the activity of sigma bond.

;Robert Bergman (Early: physical organic chemist, known for Bergman reactio

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