李艳梅有机化学1第六章.pptx
- diliao个人认证 |
- 2021-04-14 发布|
- 5.32 MB|
- 117页
Chapter 6;Content; 6.1.1 Classification 6.1.2 Nomenclature 6.1.3 Isomers (learn on your own); 6.1.1 Classification;Tertiary halo alkane;6.1.2 Nomenclature;IUPAC nomenclature;(1R,3S)-1-chloro-3-methylcyclohexane;6.1.3 Isomers (learn on your own);6.2.1 Physical properties
6.2.2 spectrum data 1 1H-NMR 2 13C-NMR 3 IR; 1H-NMR;; 13C-NMR; IR; 6.3.1 Structure and inductive effect 6.3.2 Nucleophilic substitution 6.3.3 Elimination 6.3.4 Reaction with metals 6.3.5 Reduction;1, Structure of alkyl halides 卤代烷的结构;2, Dipole moment 偶极矩;3, Inductive effect 诱导效应;;CH3;表示法;Y;-I 效应的强度;1、钥原子电负性越强, 吸电子能力越强, -I 效应越强;sp;+I 效应的强度;动态诱导效应;4, Polarizability 分子的极化 ;Inducted Dynamic Nuclear Polarization;C;Easier to break;?+;6.3.2 Nucleophilic substitution;RX;Typical examples of nucleophilic substitution 一些典型实例;2, Above